Capillary electrophoresis is an analytical technique which is used widely in diagnostic and clinical science. This book is a comprehensive account of latest capillary electrophoresis methods aimed at presenting chiral bioanalysis. The book deals with different analytical approaches regarding electrophoresis. Firstly, it discusses advanced chiral separations for the optimization of chiral resolution. Next, it deals with the upgraded model preparation for the online pre-concentration, model clean-up and methods for chemically derivatizing analytes. Lastly, it describes upgraded sequence of discovery and electrophoresis for the improvisation in qualitative and quantitative analysis. The real test of the analytical approaches is done on certain parameters of the techniques and supported by many current practical applications including chiral analysis of drugs, biodegradable materials and biological matrices. This book provides insight to the chiral electrophoresis and guides readers to work in this field to introduce innovative mechanisms and upgrade present techniques.